Chemistry S and P - Block Elements (S - Block Elements Not In Syllabus ) General Single Correct MCQ
Published on: August 14, 2026

Which is/are true statement(s)?

A
The heats of hydration of the dipositive alkaline earth metal ions decreases with an increase in their ionic size.
B
Hydration of alkali metal ion is less than that of ΙΙ A ion of the same period.
C
Alkaline earth metal ions, because of their much larger charge to radius ratio, exert a much stronger electrostatic attraction on the oxygen of water molecule surrounding them.
D
None.

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The correct answer is:
CHECK THE SOLUTION.

(a,b,c) The hydration enthalpies of alkaline earth metal ions decrease with increase in ionic size down the group.

Be 2+ > Mg 2+ > Ca 2+ > Sr 2+ > Ba 2+

The hydration enthalpies of alkaline earth metal ions are larger than those of alkali metal ions, because of their much larger charge to radius ratio, exert a much stronger electrostatic attraction on the oxygen of water molecule surrounding them. Thus, compounds of alkaline earth metals are more extensively hydrated than those of alkali metals, e.g., MgCl 2 and CaCl 2 exist as MgCl 2 .6H 2 O and CaCl 2 . 6H 2 O while NaCl and KCl do not form such hydrates. So all statements are correct.

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